The fixation of linear versus loop-type peptidic structures by metal coordination:: the coordination chemistry of Val-Val- and Val-Val-Val-bridged dicatechol ligands

被引：12

作者：

Albrecht, M

Spiess, O

Schneider, M

Weis, P

机构：

[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany

[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b200481j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Val-Val-bridged dicatechol ligand L-1-H-4 forms triplybridged dinuclear complexes with titanium(IV) ions, while the more flexible Val-Val-Val derivative L-2-H-4 leads to mixtures of complexes containing species with a cyclic arrangement of the ligand; with [cis-MoO2](2+) on the other hand, a well-defined macrocycle [(L-2)MoO2](2-) is formed which possesses a loop-type structure in the peptidic part of the ligand.

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收藏

页码：786 / 787

页数：2

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