Carbon foam derived from various precursors

被引:278
作者
Chen, C [1 ]
Kennel, EB [1 ]
Stiller, AH [1 ]
Stansberry, PG [1 ]
Zondlo, JW [1 ]
机构
[1] W Virginia Univ, Dept Chem Engn, Morgantown, WV 26505 USA
关键词
porous carbon; coal; pitch; carbonization; heat treatment; optical microscopy; SEM; mechanical properties; porosity;
D O I
10.1016/j.carbon.2005.12.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of carbon foams was developed by using low-cost precursors, such as coal, coal tar pitch and petroleum pitch. The properties of the resultant carbon foams cover a wide range, e.g., bulk density, 0.32-0.67 g/cm(3), compressive strength, 2.5-18.7 MPa, isotropic and anisotropic microstructure, etc. The investigation of foaming mechanism and the relationship between properties and structure indicate that the fluidity and dilatation of the foaming precursors significantly affect the foaming performance and foam structure. Raw coal samples were foamed directly without pretreatment in this work. However, for the pitch based foaming precursor, a thermal pretreatment is necessary to adjust its thermoplastic properties to meet the foaming requirement. The mechanical strength of carbon foam is found to be related to not only the foam cell structure, but also the fluidity and anisotropic domain size of the foaming precursors. In addition, the micro and mesopore structure in carbon foam matrix was investigated by gas adsorption and it was found that it also affects the strength of carbon foam and is related to the fluidity of foaming precursor. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1535 / 1543
页数:9
相关论文
共 25 条
[1]   A comparative study of air-blown and thermally treated coal-tar pitches [J].
Blanco, C ;
Santamaría, R ;
Bermejo, J ;
Menéndez, R .
CARBON, 2000, 38 (04) :517-523
[2]   THE EFFECT OF SELECTED ADDITIVES AND TREATMENTS ON GIESELER FLUIDITY IN COALS [J].
CLEMENS, AH ;
MATHESON, TW .
FUEL, 1995, 74 (01) :57-62
[3]   Vitreous Carbon - A New Form of Carbon [J].
Cowlard, F. C. ;
Lewis, J. C. .
JOURNAL OF MATERIALS SCIENCE, 1967, 2 (06) :507-512
[4]  
DADYBURJOR DB, 2004, PRODUCTION FOAMS FIB
[5]  
Ford W., 1964, US Patent, Patent No. [US 3121050, 3121050]
[6]   Carbon foams for thermal management [J].
Gallego, NC ;
Klett, JW .
CARBON, 2003, 41 (07) :1461-1466
[7]  
GIBSON LJ, 1997, CELLULAR SOLIDS
[8]  
Googin JM, 1967, United States patent, Patent No. [US 3345440, 3345440]
[9]  
GREGG SJ, 1982, ADSORPTION SURFACE
[10]  
HAGER JW, 1992, MATER RES SOC SYMP P, V270, P41, DOI 10.1557/PROC-270-41