An acentric parallel interpenetrated dual-ligand zinc coordination polymer from an in situ terminal-to-internal alkene rearrangement

被引：32

作者：

Brown, Kyalamboka A.

Martin, David P.

LaDuca, Robert L. ^{[1
]}

机构：

[1] Michigan State Univ, Lyman Briggs Coll, E Lansing, MI 48825 USA

来源：

CRYSTENGCOMM | 2008年 / 10卷 / 10期

关键词：

D O I：

10.1039/b809255a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination polymer [Zn(mesaconate)(dpa)](n) (1, dpa = 4,4'-dipyridylamine) has been prepared from the hydrothermal treatment of zinc chloride, dpa, and itaconic acid. An in situ terminal alkene to internal alkene isomerization occurred during self-assembly, unprecedented in coordination polymer chemistry. Single-crystal X-ray diffraction revealed that 1 crystallizes in the acentric space group Aba2, and features a parallel doubly interpenetrated (4,4)-rectangular layer morphology. Interlayer hydrogen bonding mediated by the dpa ligand results in a doubly interpenetrated (3,5)-connected supramolecular lattice with a novel (4(2)6)(4(2)6(5)8(3)) topology. Compound 1 undergoes blue-light emission upon exposure to ultraviolet radiation.

引用

收藏

页码：1305 / 1308

页数：4

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