A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4- cluster

被引：204

作者：

Custelcean, R ^{[1
]}

Gorbunova, MG ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 47期

关键词：

D O I：

10.1021/ja055528o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H2O)4- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster. Copyright © 2005 American Chemical Society.

引用

页码：16362 / 16363

页数：2

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