Synthesis of substituted conjugated polymers: Tuning properties by functionalization

被引：23

作者：

Farinola, Gianluca M. ^{[1
]}

Babudri, Francesco ^{[1
,2
]}

Cardone, Antonio ^{[2
]}

Hassan Omar, Omar ^{[2
]}

Naso, Francesco ^{[1
,2
]}

机构：

[1] Univ Bari, Dept Chem, Bari, Italy

[2] CNR ICCOM, Bari, Italy

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 08期

关键词：

conjugated polymers; organic synthesis; organic semiconductors; cross-coupling reactions; chiral polymers; fluorinated polymers;

D O I：

10.1351/pac200880081735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review addresses features of special interest concerning two classes of functionalized semiconducting polymers: poly(aryleneethynylene)s (PAEs) bearing biomolecules as chiral nonracemic pendant groups and poly(phenylenevinylene)s (PPVs), which are fluorinated in various positions of the repeating units. Molecular design and choice of specific substituents, synthetic protocols. and the effect of functionalization on properties of the polymers both in solution and in the solid state are discussed.

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页码：1735 / 1746

页数：12

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