Molybdenum-catalyzed asymmetric allylic alkylations

被引：160

作者：

Belda, O ^{[1
]}

Moberg, C ^{[1
]}

机构：

[1] Royal Inst Technol, Dept Chem Organ Chem, SE-10044 Stockholm, Sweden

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2004年 / 37卷 / 03期

关键词：

D O I：

10.1021/ar030239v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly regio- and enantioselective molybdenum-catalyzed allylic alkylation reaction has become a powerful synthetic tool during the past few years. This Account describes the achievements gained so far in the area, with special attention directed to the different chiral ligands that have been used for inducing chirality in the products, the range of allylic substrates and nucleophiles employed, mechanistic studies, and applications of the reaction in asymmetric syntheses.

引用

页码：159 / 167

页数：9

共 44 条

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