Bright White Upconversion Emission from Tm3+/Yb3+/Er3+-Doped Lu3Ga5O12 Nanocrystals

被引:142
作者
Mahalingam, Venkataramanan [1 ]
Mangiarini, Francesca [1 ]
Vetrone, Fiorenzo [2 ]
Venkatramu, Vemula [3 ]
Bettinelli, Marco [4 ,5 ]
Speghini, Adolfo [5 ,6 ]
Capobianco, John A. [1 ]
机构
[1] Concordia Univ, Dept Chem & Biochem, Montreal, PQ, Canada
[2] Univ Quebec, Inst Natl Rech Sci Energie Mat & Telecommun, Ste Foy, PQ G1V 2M3, Canada
[3] Yogi Vemana Univ, Dept Phys, Kadapa, India
[4] Univ Verona, Dipartimento Sci & Tecnol, I-37100 Verona, Italy
[5] INSTM, UdR Verona, Verona, Italy
[6] Univ Verona, DiSTeMeV, I-37100 Verona, Italy
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1021/jp8076479
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the synthesis of Tm3+/Yb3+/Er3+-doped Lu3Ga5O12 nanocrystals prepared by a simple sol-gel method exhibiting bright white light following excitation with lower energy near-infrared light (lambda(exc) = 980 nm) via an upconversion process. The combination of upconverted blue (from Tm3+), green, and red (from Er3+) emissions resulted in the white luminescence, which is intense and visible to the naked eye at a laser power less than 30 mW (3.4 W/cm(2)). The calculated Commission internationale de l'eclairage (CIE) color coordinates, which is the standard reference for defining colors, fall well within the white region and shift only slightly with the incident laser powers indicating that the material might be promising for the development of devices such as white light lasers and LEDs.
引用
收藏
页码:17745 / 17749
页数:5
相关论文
共 28 条
[1]   Upconversion and anti-stokes processes with f and d ions in solids [J].
Auzel, F .
CHEMICAL REVIEWS, 2004, 104 (01) :139-173
[2]  
Blasse G., 1994, LUMINESCENT MAT, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1]
[3]   Bright white upconversion luminescence in rare-earth-ion-doped Y2O3 nanocrystals [J].
Chen, G. Y. ;
Liu, Y. ;
Zhang, Y. G. ;
Somesfalean, G. ;
Zhang, Z. G. ;
Sun, Q. ;
Wang, F. P. .
APPLIED PHYSICS LETTERS, 2007, 91 (13)
[4]   White organic light-emitting devices for solid-state lighting [J].
D'Andrade, BW ;
Forrest, SR .
ADVANCED MATERIALS, 2004, 16 (18) :1585-1595
[5]   Spectroscopy of Nd3+ and Yb3+ codoped fluoroindogallate glasses [J].
de Sousa, DF ;
Batalioto, F ;
Bell, MJV ;
Oliveira, SL ;
Nunes, LAO .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (07) :3308-3313
[6]   Applications of magneto-optical waveguides in integrated optics:: review [J].
Dötsch, H ;
Bahlmann, N ;
Zhuromskyy, O ;
Hammer, M ;
Wilkens, L ;
Gerhardt, R ;
Hertel, P ;
Popkov, AF .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2005, 22 (01) :240-253
[7]  
*ICDD, 000130400 PDF ICDD
[8]   Laser crystals and ceramics: recent advances [J].
Kaminskii, Alexander A. .
LASER & PHOTONICS REVIEWS, 2007, 1 (02) :93-177
[9]   Near-infrared-electroluminescent light-emitting planar optical sources based on gallium nitride doped with rare earths [J].
Kim, JH ;
Holloway, PH .
ADVANCED MATERIALS, 2005, 17 (01) :91-+
[10]   Optical and structural properties of Pr:GGG crystalline thin film waveguides grown by pulsed-laser deposition [J].
Lancok, J ;
Garapon, C ;
Jelinek, M ;
Mugnier, J ;
Brenier, R .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2005, 81 (07) :1477-1483