Microscopic friction anisotropy and asymmetry related to the molecular tilt azimuth in a monolayer of glycerol ester

被引:14
作者
Hisada, K [1 ]
Knobler, CM
机构
[1] Fukui Univ, Fac Engn, Dept Appl Chem & Biotechnol, Fukui 9108507, Japan
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
关键词
lateral force microscopy; friction anisotropy; friction asymmctry; 1-monoalkyl-rac-glycerol; Langmuir-Blodgett film;
D O I
10.1016/S0927-7757(01)00910-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The molecular tilt azimuth in domains of a condensed phase in monolayers of 1-monopalmitoyl-rac-glycerol and 1-monostearoyl-rac-glycerol at the air/water interface exhibits a regular star texture. Lateral-force microscopy has been used to investigate the friction behavior of these monolayers that have been transferred onto silicon substrates. The condensed domains revealed strong friction anisotropies and asymmetries. The angular dependence of these properties correlates well with the tilt azimuth of the alkyl tails in the monolayer. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:21 / 30
页数:10
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