Near-infrared quantum cutting in transparent nanostructured glass ceramics

被引:180
作者
Chen, Daqin [1 ]
Wang, Yuansheng [1 ]
Yu, Yunlong [1 ]
Huang, Ping [1 ]
Weng, Fangyi [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
关键词
D O I
10.1364/OL.33.001884
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Quantum cutting downconversion involving the emission of two near-infrared photons for each blue photon absorbed is realized in transparent glass ceramics with embedded Pr3+/Yb3+: beta-YF3 nanocrystals. On excitation of Pr3+ ions with a visible photon at 482 nm, Yb3+ ions emit two near-infrared photons at 976 nm through an efficient cooperative energy transfer from Pr3+ to Yb3+, with optimal quantum efficiency close to 200%. The development of the near-infrared quantum cutting transparent glass ceramic could open a route to enhance the energy efficiency of the silicon solar cell by converting one blue solar photon to two near-infrared ones. (C) 2008 Optical Society of America.
引用
收藏
页码:1884 / 1886
页数:3
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