Electron spin catalysis

被引:150
作者
Buchachenko, AL [1 ]
Berdinsky, VL [1 ]
机构
[1] Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
关键词
D O I
10.1021/cr010370l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Spin catalysis was proved to operate in radical recombination, biradical decay, cis-trans isomerization of molecules, low-temperature recombination of spin-aligned hydrogen atoms, spin conversion of positronium atom, primary light-harvesting reactions in photosynthetic centers, paramagnetic quenching of excited molecules among others. Possibly the extent of the phenomenon may be larger than the level of current knowledge. As a driving force of spin conversion in triads, the exchange interaction competes with magnetic interactions in the pairs of spin carriers.
引用
收藏
页码:603 / 612
页数:10
相关论文
共 48 条
[1]  
Agren H., 1996, ADV QUANTUM CHEM, V27, P71, DOI DOI 10.1016/S0065-3276(08)60251-8
[2]   Increasing the heavy atom effect of xenon by adsorption to zeolites: Photolysis of 2,3-diazabicyclo[2.2.2]oct-2-ene [J].
Anderson, MA ;
Grissom, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (40) :9552-9556
[3]   Electron spin catalysis by xenon in an enzyme [J].
Anderson, MA ;
Xu, YP ;
Grissom, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6720-6721
[4]   PHOTOLYSIS OF 2,3-DIAZABICYCLO[2.2.2]OCT-2-ENE - ELECTRONIC SPIN DETERMINES THE DISTRIBUTION OF PRODUCTS [J].
ANDERSON, MA ;
GRISSOM, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) :5041-5048
[5]   OBSERVATIONS OF HEISENBERG SPIN EXCHANGE BETWEEN REACTIVE FREE-RADICALS [J].
BARTELS, DM ;
TRIFUNAC, AD ;
LAWLER, RG .
CHEMICAL PHYSICS LETTERS, 1988, 152 (01) :109-115
[6]  
Buchachenko A.L., 1994, CHEM GENERATION RECE
[7]  
Buchachenko A. L, 1984, SPIN POLARIZATION MA
[8]   Spin catalysis of chemical reactions [J].
Buchachenko, AL ;
Berdinsky, VL .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (47) :18292-18299
[9]   SPIN CATALYSIS OF THE RADICAL RECOMBINATION REACTION [J].
BUCHACHENKO, AL ;
RUBAN, LV ;
STEP, EN ;
TURRO, NJ .
CHEMICAL PHYSICS LETTERS, 1995, 233 (03) :315-318
[10]  
Buchachenko AL, 1998, KINET CATAL+, V39, P301