Heteropoly acid as a novel efficient catalyst for Fries rearrangement

被引：71

作者：

Kozhevnikova, EF ^{[1
]}

Derouane, EG ^{[1
]}

Kozhevnikov, IV ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 11期

关键词：

D O I：

10.1039/b202148j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heteropoly acid H3PW12O40 is a very efficient and environmentally benign catalyst for the Fries rearrangement of phenyl acetate in homogeneous or heterogeneous liquid-phase systems at 100-150degreesC.

引用

页码：1178 / 1179

页数：2

共 12 条

[1]

[Anonymous], J MOL CATAL A

[2] Zeolite catalysts as solid solvents in fine chemicals synthesis - 2. Competitive adsorption of the reactants and products in the Friedel-Crafts acetylations of anisole and toluene [J].

Derouane, EG ;

Crehan, G ;

Dillon, CJ ;

Bethell, D ;

He, H ;

Derouane-Abd Hamid, SB .

JOURNAL OF CATALYSIS, 2000, 194 (02) :410-423

[3]

GUISNET M, 2001, FINE CHEM HETEROGENE, P211

[4] Silica-included heteropoly compounds as solid acid catalysts [J].

Izumi, Y ;

Ono, M ;

Kitagawa, M ;

Yoshida, M ;

Urabe, K .

MICROPOROUS MATERIALS, 1995, 5 (04) :255-262

[5]

Izumi Y., 1992, Zeolite, Clay and Heteropoly Acid in Organic Reactions

[6] Solvent effects in liquid phase Fries rearrangement of phenyl acetate over a HBEA zeolite [J].

Jayat, F ;

Picot, MJS ;

Guisnet, M .

CATALYSIS LETTERS, 1996, 41 (3-4) :181-187

[7] Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions [J].

Kozhevnikov, IV .

CHEMICAL REVIEWS, 1998, 98 (01) :171-198

[8] Study of catalysts comprising heteropoly acid H3PW12O40 supported on MCM-41 molecular sieve and amorphous silica [J].

Kozhevnikov, IV ;

Kloetstra, KR ;

Sinnema, A ;

Zandbergen, HW ;

vanBekkum, H .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 114 (1-3) :287-298

[9]

Metivier P., 2001, FINE CHEM HETEROGENE, P161

[10]

Okuhara T, 1996, ADV CATAL, V41, P113, DOI 10.1016/S0360-0564(08)60041-3

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