Computer analyses of complex kinetics containing equilibrium processes. Example of application for unusual atropisomerization of a tetraphenylporphyrin derivative

被引：8

作者：

Kuroda, Y

Kawashima, A

Ogoshi, H

机构：

来源：

CHEMISTRY LETTERS | 1996年 / 01期

关键词：

D O I：

10.1246/cl.1996.57

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic behavior of atropisomerization of tetraphenylporphyrin derivative containing equilibrium processes of dimer formation were analyzed directly by a non-linear least square optimization method which uses numerical integration of kinetic differential equations. Analyses clearly indicate a kinetic model determined with one rate and two equilibrium constants as the most plausible mechanism.

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页码：57 / 58

页数：2

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