Multiple syntheses of (C5Me5)3U

被引：92

作者：

Evans, WJ ^{[1
]}

Nyce, GW ^{[1
]}

Forrestal, KJ ^{[1
]}

Ziller, JW ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 06期

关键词：

D O I：

10.1021/om010831t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new synthetic routes to the sterically crowded (C5Me5)(3)U complex have been developed. (C5Me5)(3)U can be prepared by (a) reaction of [(C5Me5)(2)UH2](2) with tetramethylfulvene, (b) reduction of (C5Me5)(2)Pb with (C5Me5)(2)UH(DMPE), (c) reaction of [(C5Me5)(2)U- (L)](+) (L = THF, DMPE) with K(18-crown-6)(C5Me5), and (d) reaction of [(C5Me5)(2)U][BPh4] with KC5Me5. Reaction of (C5Me5)(2)UH(DMPE) with C8H8 forms the product of the (C5Me5)(3)U/C8H8 reaction, [(C8H8)(C5Me5)U](2)(C8H8). The X-ray crystal structures of the (C5Me5)(2)U-[N(SiMe3)(2)] and [(C5Me5)(2)U][BPh4] precursors used in this study are reported, as well as the convenient synthesis of a new trivalent uranium precursor, (C5Me5)(2)UMe2K.

引用

收藏

页码：1050 / 1055

页数：6

相关论文

共 47 条

[1]

[Anonymous], 1992, INT TABLES XRAY CRYS, VC

[2]

[Anonymous], 1999, SMART SOFTW US GUID

[3] A CONVENIENT ENTRY INTO TRIVALENT ACTINIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF ANI3(THF)4 AND AN[N(SIME3)2]3 (AN=U, NP, PU) [J].

AVENS, LR ;

BOTT, SG ;

CLARK, DL ;

SATTELBERGER, AP ;

WATKIN, JG ;

ZWICK, BD .

INORGANIC CHEMISTRY, 1994, 33 (10) :2248-2256

[4] Mono(pentamethylcyclopentadienyl)uranium(III) complexes:: Synthesis, properties, and X-ray structures of (η-C5Me5)UI2(THF)3, (η-C5Me5)UI2(py)3, and (η-C5Me5)U[N(SiMe3)2]2 [J].

Avens, LR ;

Burns, CJ ;

Butcher, RJ ;

Clark, DL ;

Gordon, JC ;

Schake, AR ;

Scott, BL ;

Watkin, JG ;

Zwick, BD .

ORGANOMETALLICS, 2000, 19 (04) :451-457

[5] SYNTHESIS OF THORIUM AMIDE COMPLEXES VIA HALIDE METATHESIS AND TRANSAMINATION PROCEDURES - X-RAY STRUCTURE OF TH[N(SIME(3))(2)](2)(NMEPH)(2) [J].

BARNHART, DM ;

CLARK, DL ;

GRUMBINE, SK ;

WATKIN, JG .

INORGANIC CHEMISTRY, 1995, 34 (07) :1695-1699

[6] SYNTHESIS AND SOME REACTIONS OF TRIS(CYCLOPENTADIENYL) - URANIUM(IV) HYDRIDES - CRYSTAL-STRUCTURE OF [U(C5H4BU(T))3H] [J].

BERTHET, JC ;

LEMARECHAL, JF ;

LANCE, M ;

NIERLICH, M ;

VIGNER, J ;

EPHRITIKHINE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (09) :1573-1577

[7] Synthesis and crystal structure of [U(eta-C5Me5)(2)(OC4H8)(2)][BPh4], the first cationic cyclopentadienyl compound of uranium(III) [J].

Boisson, C ;

Berthet, JC ;

Ephritikhine, M ;

Lance, M ;

Nierlich, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 533 (1-2) :7-11

[8] PREPARATION OF YB[N(SIME3)2]2[AIME3]2 - A COMPLEX WITH 4 YB-ME-AL INTERACTIONS [J].

BONCELLA, JM ;

ANDERSEN, RA .

ORGANOMETALLICS, 1985, 4 (01) :205-206

[9] SYNTHESIS, CHARACTERIZATION, AND X-RAY STRUCTURE OF THE URANIUM THIOLATE COMPLEX U(S-2,6-ME2C6H3)[N(SIME3)2]3 [J].

CLARK, DL ;

MILLER, MM ;

WATKIN, JG .

INORGANIC CHEMISTRY, 1993, 32 (05) :772-774

[10] SYNTHESIS OF MONOMERIC PERMETHYLYTTROCENE DERIVATIVES - THE CRYSTAL-STRUCTURES OF ETA-5-C5H5YN(SIME3)2 AND ETA-5-C5H5YCH(SIME3)2 [J].

DENHAAN, KH ;

DEBOER, JL ;

TEUBEN, JH ;

SPEK, AL ;

KOJICPRODIC, B ;

HAYS, GR ;

HUIS, R .

ORGANOMETALLICS, 1986, 5 (08) :1726-1733

← 1 2 3 4 5 →