Stretched polymers in a poor solvent

被引:53
作者
Grassberger, P [1 ]
Hsu, HP [1 ]
机构
[1] Forschungszentrum Julich, John Neumann Inst Comp, D-52425 Julich, Germany
来源
PHYSICAL REVIEW E | 2002年 / 65卷 / 03期
关键词
D O I
10.1103/PhysRevE.65.031807
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Stretched polymers with attractive interaction are studied in two and three dimensions. They are described by biased self-avoiding random walks with nearest-neighbor attraction. The bias corresponds to opposite forces applied to the first and last monomers. We show that both in d=2 and d=3 a phase transition occurs as this force is increased beyond a critical value, where the polymer changes from a collapsed globule to a stretched configuration. This transition is second order in d=2 and first order in d=3. For d=2 we predict the transition point quantitatively from properties of the unstretched polymer. This is not possible in d=3, but even there we can estimate the transition point precisely, and we can study the scaling at temperatures slightly below the collapse temperature of the unstretched polymer. We find very large finite size corrections that would make very difficult the estimate of the transition point from straightforward simulations.
引用
收藏
页码:1 / 031807
页数:9
相关论文
共 34 条
[1]  
[Anonymous], 2001, SPRINGER SERIES STAT
[2]   Two-dimensional oriented self-avoiding walks with parallel contacts [J].
Barkema, GT ;
Bastolla, U ;
Grassberger, P .
JOURNAL OF STATISTICAL PHYSICS, 1998, 90 (5-6) :1311-1324
[3]   ENTROPIC ELASTICITY OF LAMBDA-PHAGE DNA [J].
BUSTAMANTE, C ;
MARKO, JF ;
SIGGIA, ED ;
SMITH, S .
SCIENCE, 1994, 265 (5178) :1599-1600
[4]   THE BOND FLUCTUATION METHOD - A NEW EFFECTIVE ALGORITHM FOR THE DYNAMICS OF POLYMERS IN ALL SPATIAL DIMENSIONS [J].
CARMESIN, I ;
KREMER, K .
MACROMOLECULES, 1988, 21 (09) :2819-2823
[5]  
de Gennes P.G., 1979, SCALING CONCEPTS POL
[6]   OPTIMIZED MONTE-CARLO DATA-ANALYSIS [J].
FERRENBERG, AM ;
SWENDSEN, RH .
PHYSICAL REVIEW LETTERS, 1989, 63 (12) :1195-1198
[7]   NEW MONTE-CARLO TECHNIQUE FOR STUDYING PHASE-TRANSITIONS [J].
FERRENBERG, AM ;
SWENDSEN, RH .
PHYSICAL REVIEW LETTERS, 1988, 61 (23) :2635-2638
[8]   Micromechanism of the deformation process of macromolecular systems [J].
Goritz, D ;
Kreitmeier, S ;
Wittkop, M .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1996, B35 (3-4) :615-627
[9]   SIMULATIONS OF 3-DIMENSIONAL THETA-POLYMERS [J].
GRASSBERGER, P ;
HEGGER, R .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (17) :6881-6899
[10]   Pruned-enriched Rosenbluth method: Simulations of theta polymers of chain length up to 1,000,000 [J].
Grassberger, P .
PHYSICAL REVIEW E, 1997, 56 (03) :3682-3693