A comparative study of m-cresol treated polyaniline and Langmuir Blodgett films

被引：10

作者：

da Silva, JEP

de Torresi, SIC

Temperini, MLA

Gonçalves, D

Oliveira, ON

机构：

[1] Univ Sao Paulo, Dept Quim Fundamental, Inst Quim, BR-05599970 Sao Paulo, Brazil

[2] Univ Sao Paulo, Inst Fis, Sao Carlos, SP, Brazil

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

基金：

巴西圣保罗研究基金会;

关键词：

polyaniline; Raman spectroscopy; secondary doping; Langmuir Blodgett films;

D O I：

10.1016/S0379-6779(98)00801-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polyaniline films prepared by Langmuir-Blodgett technique were characterized by X- Ray diffractometry and Raman spectroscopy. The obtained results were compared with those from secondarily doped samples treated with HCSA and m-cresol. When LB films were doped with HCl vapour, the Raman spectrum obtained is different form that of PANI/HCl samples prepared by chemical or electrochemical polymerization, being very close to spectrum of PANI/CSA/m-cresol samples. In LB films a great increase in the intensity of the band correponding to free carriers indicates the important role played by the extended conformation and conductivity.

引用

页码：691 / 691

页数：1