Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

被引：173

作者：

Yang, Sihai ^{[1
]}

Lin, Xiang ^{[1
]}

Blake, Alexander J. ^{[1
]}

Thomas, K. Mark ^{[2
,3
]}

Hubberstey, Peter ^{[1
]}

Champness, Neil R. ^{[1
]}

Schroeder, Martin ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Newcastle Univ, No Carbon Res Labs, Sir Joseph Swan Inst Energy Res, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b814155j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

H-2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H-2 adsorption than the parent material, indicating that the increase in H-2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.

引用

页码：6108 / 6110

页数：3

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