p-Anisaldyhyde as a ligand in molybdenum and tungsten complexes: sigma or pi?

被引：15

作者：

Schuster, DM ^{[1
]}

White, PS ^{[1
]}

Templeton, JL ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,W R KENAN JR LABS,CHAPEL HILL,NC 27599

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 26期

关键词：

D O I：

10.1021/om960869j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The different binding modes of p-anisaldehyde to the [TpMo(CO)(MeC=CMe)](+) and [TpW(CO)(MeC=CMe)](+) fragments in solution have been assessed by IR and H-1 and C-13 NMR spectra. X-ray analyses substantiate that p-anisaldehyde is a-bound in, the molybdenum complex 1 and pi-bound in the tungsten complex 2.

引用

页码：5467 / 5469

页数：3

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