Stability of W/O and W/O/W emulsions as a result of partial solidification

被引:33
作者
Clausse, D [1 ]
Pezron, I [1 ]
Komunjer, L [1 ]
机构
[1] Univ Technol Compiegne, Ctr Rech Royallieu, Dept Genie Chim,CNRS UPRESA 6067, Div Thermodynam & Physicochim Procedes Ind, F-60205 Compiegne, France
关键词
emulsion stability; solidification; mass transfer; ripening;
D O I
10.1016/S0927-7757(98)00853-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This communication reviews the drastic modifications that may occur within emulsions when they are submitted to temperature variations during manufacturing, storage, transport and use. Emphasis will be given to the modifications resulting from changes after solidification. Pathways of solidification of W/O and W/O/W emulsions will be presented. Due to the specific structure of the emulsions under study (simple or multiple) only partial solidification may be obtained. This situation, out of thermodynamic equilibrium, may lead to a water transfer across the oil phase. Resulting emulsion transformation and destabilization are examined. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:23 / 29
页数:7
相关论文
共 12 条
[1]   STUDY OF FREEZING OF SUPERCOOLED WATER DISPERSED WITHIN EMULSIONS BY DIFFERENTIAL SCANNING CALORIMETRY [J].
BROTO, F ;
CLAUSSE, D .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1976, 9 (23) :4251-4257
[2]   KINETICS OF ICE NUCLEATION IN AQUEOUS EMULSIONS [J].
CLAUSSE, D ;
BABIN, L ;
BROTO, F ;
AGUERD, M ;
CLAUSSE, M .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (21) :4030-4034
[3]   PHASE-TRANSFORMATIONS IN EMULSIONS .1. EFFECTS OF THERMAL TREATMENTS ON NUCLEATION PHENOMENA - EXPERIMENTS AND MODEL [J].
CLAUSSE, D ;
DUMAS, JP ;
MEIJER, PHE ;
BROTO, F .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 1987, 8 (01) :1-28
[4]   ON THE STUDY BY DSC OF THE UNEXPECTED ICE MELTING AT O-DEGREES-C OF EMULSIFIED AQUEOUS SALINE SOLUTIONS [J].
CLAUSSE, D ;
SIFRINI, I ;
DUMAS, JP .
THERMOCHIMICA ACTA, 1987, 122 (01) :123-133
[5]   INFLUENCE OF A PRECOOLING ON THE NUCLEATION KINETICS OF ICE FROM WATER DROPLETS [J].
CLAUSSE, D ;
BROTO, F .
COLLOID AND POLYMER SCIENCE, 1982, 260 (06) :641-642
[6]  
CLAUSSE D, 1991, ADV MEASUREMENT CONT
[7]  
Dufour L., 1963, Thermodynamics of clouds
[8]   STUDY OF THERMOGRAMS OBTAINED THROUGH DIFFERENTIAL SCANNING CALORIMETRY OF AN EMULSION OF A SUPERCOOLED LIQUID [J].
DUMAS, JP ;
CLAUSSE, D ;
BROTO, F .
THERMOCHIMICA ACTA, 1975, 13 (03) :261-275
[9]   DIELECTRIC STUDY OF MONOTHERMAL FREEZING OF SUPERCOOLED WATER DISPERSED WITHIN EMULSIONS - PRELIMINARY REPORT [J].
LACHAISE, J ;
CLAUSSE, M .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1975, 8 (10) :1227-1231
[10]   STUDY OF STATE TRANSITIONS WITHIN MULTIPLE W/O/W EMULSIONS USING CALORIMETRY (DSC) [J].
POTIER, L ;
RAYNAL, S ;
SEILLER, M ;
GROSSIORD, JL ;
CLAUSSE, D .
THERMOCHIMICA ACTA, 1992, 204 (01) :145-155