Luminescent Triarylboron-Functionalized Zinc Carboxylate Metal-Organic Framework

被引：54

作者：

Blight, Barry A. ^{[1
]}

Guillet-Nicolas, Remy ^{[2
]}

Kleitz, Freddy ^{[2
]}

Wang, Rui-Yao ^{[1
]}

Wang, Suning ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Univ Laval, Dept Chem, Quebec City, PQ G1V 0A6, Canada

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

PROTON CONDUCTION; HYDROGEN; MOFS; MOLECULES; EMISSION; STORAGE;

D O I：

10.1021/ic3020223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a (ZnB)-B-II-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and similar to 21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N-2, argon, and CO2.

引用

页码：1673 / 1675

页数：3

共 58 条

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