Correlation of metal spin state with catalytic reactivity:: Polymerizations mediated by α-diimine-iron complexes

被引：92

作者：

Shaver, MP ^{[1
]}

Allan, LEN ^{[1
]}

Rzepa, HS ^{[1
]}

Gibson, VC ^{[1
]}

机构：

[1] Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 08期

关键词：

alpha-diimines; homogeneous catalysis; iron; polymerization; spin state;

D O I：

10.1002/anie.200502985

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of styrene polymerization by α-diimine iron complexes correlates with the metal spin state of the catalyst. Experimental and theoretical studies indicate that high-spin catalysts are halogenophilic, resulting in atom transfer radical polymerization (ATRP), while intermediate-spin complexes are carbophilic giving rise to catalytic chain transfer (CCT, see graph). (Graph Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1241 / 1244

页数：4

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