Synthesis and reactivity of the octahedral d6 parent amido complexes TpRu(L)(L′)(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L′ PMe3, P(OMe)3; L = CO, L′ PPh3) and [TpRu(PPh3)(NH2)2][Li]

被引：44

作者：

Jayaprakash, KN ^{[1
]}

Conner, D ^{[1
]}

Gunnoe, TB ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 25期

关键词：

D O I：

10.1021/om010739x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of octahedral ruthenium (II) parent amido complexes of the type TpRu(L)(L')(NH2) (L/L' = neutral and two-electron-donor ligands) and [TpRu-(PPh3)(NH2)(2)][Li] (Tp = hydridotris(pyrazolyl)borate) have been prepared. Preliminary reactivity studies indicate that the amido moieties are highly basic: for example, TpRu(L)(L')(NH2) complexes deprtonate phenylacetylene at room temperature to form [TpRu(L)(L')(NH3)][PhC2] ion pairs, as determined by H-1 NMR spectroscopy.

引用

页码：5254 / 5256

页数：3

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