C-H activation by a diplatinum(II) complex:: Isolation and structures of [Pt2(CH3)(SMe2)Ph2(ttab)][BAr′4] and [Pt2(H2O)2Ph2(ttab)][BAr′4]2 (ttab=1,2,4,5-tetrakis(1-N-7-azaindolyl)benzene)

被引：23

作者：

Song, DT ^{[1
]}

Jia, WL ^{[1
]}

Wang, SM ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 06期

关键词：

D O I：

10.1021/om0341449

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear Pt(II) complex Pt-2(CH3)(4)(ttab) (1; ttab = 1,2,4,5-tetrakis(1-N-7-azaindolyl)benzene) has been found to activate multiple benzene molecules by cleaving a C-H bond in the presence of[H(Et2O)(2)][BAr'(4)] (Ar' = 3,5-bis(trifluoromethyl)phenyl). The unprecedented dinuclear Pt(H) product [Pt-2(CH3)(SMe2)Ph-2(ttab)][BAr'(4)] (2), which contains two phenyl groups on one Pt(H) center, has been isolated from the 1:1 reaction of 1 with [H(Et2O)(2)][BAr'(4)]. The novel dinuclear Pt(H) complex [Pt-2(H2O)(2)Ph-2(ttab)][BAr'(4)](2) (3) has been isolated from the 1:2 reaction of 1 with [H(Et2O)(2)][BAr'(4)] when reagent-grade solvents were used in the recrystallization process. The structures of 2 and 3 have been established by X-ray diffraction analyses.

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页码：1194 / 1196

页数：3

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