Rare earth coordination polymers with zeolite topology constructed from 4-connected building units

被引：138

作者：

Guo, Xiaodan ^{[1
]}

Zhu, Guangshan ^{[1
]}

Li, Zhongyue ^{[1
]}

Chen, Yan ^{[1
]}

Li, Xiaotian ^{[1
]}

Qiu, Shilun ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 10期

关键词：

D O I：

10.1021/ic060116h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of rare earth coordination polymers, M(BTC)(DMF)( DMSO) ( M = Tb ( 1), Ho ( 2), Er ( 3), Yb ( 4), Y( 5)), with zeolite ABW topology have been synthesized under mild conditions. They exhibit the same three-dimensional (3D) architecture and crystallize in monoclinic symmetry space group P2(1)/n. Their structures are built up from inorganic and organic 4-connected building units, whose vertex symbols are 4, 4, 6, 6, 6, 8. The building units link to each other to generate approximate 5 x 8 angstrom(2) channels along the [ 100] direction. The luminescent and magnetic properties of these compounds are investigated, and the results reveal that they could be anticipated to be potential antiferromagnetic and fluorescent materials.

引用

页码：4065 / 4070

页数：6

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