Magnetic Properties of NiIICrIII Layered Double Hydroxide Materials

被引：37

作者：

Almansa, Juan J. ^{[1
]}

Coronado, Eugenio ^{[1
]}

Marti-Gastaldo, Carlos ^{[1
]}

Ribera, Antonio ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, Valencia 46980, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 36期

关键词：

Layered compounds; Chromium; Nickel; Magnetic properties; Spin frustration;

D O I：

10.1002/ejic.200800658

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper describes the isolation of four layered double hydroxide (LDH) compounds having the general formula [(Ni3-xCrxIII)-Cr-II(OH)(6)](CO3)(x/2)center dot yH(2)O [x = 0.57 (1), 0.69 (2), 0.81 (3) and 0.93 (4)] by using homogeneous precipitation methods and varying the metal ratio in the synthetic solutions. All the reported compounds have carbonate anions in the interlamellar space. This fact forces the interlayer distances to remain unchanged in all the cases, thus providing an ideal system in which the changes observed in magnetic properties can be correlated with metal composition along the hydroxide layers. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

引用

页码：5642 / 5648

页数：7

共 47 条

[1] Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction-control of size and morphology [J].

Adachi-Pagano, M ;

Forano, C ;

Besse, JP .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (08) :1988-1993

[2] Direct intercalation of amino acids into layered double hydroxides by coprecipitation [J].

Aisawa, S ;

Takahashi, S ;

Ogasawara, W ;

Umetsu, Y ;

Narita, E .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (01) :52-62

[3] Thermal behaviour of hydroxides, hydroxysalts and hydrotalcites [J].

Bera, P ;

Rajamathi, M ;

Hegde, MS ;

Kamath, PV .

BULLETIN OF MATERIALS SCIENCE, 2000, 23 (02) :141-145

[4]

BRICKENHORFF WB, 1996, J APPL PHYS, V79, P6147

[5]

BRINDLEY GW, 1979, AM MINERAL, V64, P836

[6] A NEW 2-DIMENSIONAL APPROACH TO MOLECULAR-BASED MAGNETS - NICKEL(II)-CHROMIUM(III) DOUBLE HYDROXIDE SYSTEMS [J].

BUJOLIDOEUFF, M ;

FORCE, L ;

GADET, V ;

VERDAGUER, M ;

ELMALKI, K ;

DEROY, A ;

BESSE, JP ;

RENARD, JP .

MATERIALS RESEARCH BULLETIN, 1991, 26 (07) :577-587

[7] CHARACTERIZATION AND CATALYTIC ACTIVITY OF COBALT CHROMIUM MIXED OXIDES [J].

BUSCA, G ;

TRIFIRO, F ;

VACCARI, A .

LANGMUIR, 1990, 6 (09) :1440-1447

[8] Magnetic ordering and spin-glass behavior in first-row transition metal hexacyanomanganate(IV) Prussian blue analogues [J].

Buschmann, WE ;

Miller, JS .

INORGANIC CHEMISTRY, 2000, 39 (11) :2411-2421

[9] NANOSCALE IMAGING OF MOLECULAR ADSORPTION [J].

CAI, H ;

HILLIER, AC ;

FRANKLIN, KR ;

NUNN, CC ;

WARD, MD .

SCIENCE, 1994, 266 (5190) :1551-1555

[10] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

← 1 2 3 4 5 →