Ready access to the 6,8-dioxabicyclo[3.2.1]octane ring system using asymmetric heterocycloaddition induced by a chiral sulfoxide:: application to the total synthesis of the Mus musculus pheromone

被引：15

作者：

Hayes, P ^{[1
]}

Maignan, C ^{[1
]}

机构：

[1] Fac Sci, ESA 6011, Organ Synth Lab, F-72085 Le Mans 9, France

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(99)00070-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new stereocontrolled total synthesis of the (1R,5S,7R)-exo-6,8-dioxabicycio[3.2.1]oct-3-ene skeleton of the Mus musculus pheromone has been achieved via an asymmetric intermolecular Diels-Alder reaction and an intramolecular conjugated addition, controlled by a chiral auxiliary. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：1041 / 1050

页数：10

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