Functional resins as hydrophilic supports for nanoclustered Pd(0) and Pd(0)-Au(0) catalysts designed for the direct synthesis of hydrogen peroxide

被引：45

作者：

Burato, C ^{[1
]}

Centomo, P ^{[1
]}

Rizzoli, M ^{[1
]}

Biffis, A ^{[1
]}

Campestrini, S ^{[1
]}

Corain, B ^{[1
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35100 Padua, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2006年 / 348卷 / 1-2期

关键词：

functional cross-linked polymer; hydrogen; hydrogen peroxide; oxygen; palladium;

D O I：

10.1002/adsc.200505208

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The commercial macroreticular cation exchanger resin Lewatit K2621/H+ and two gel-type resins bearing -SO3H and -SMe functionalities are used to produce two acidic Pd(O)/resin(H+) and one non-acidic Pd(0)-Au(0)/resin catalysts that are tested in the direct synthesis of H2O2 in methanol/ water (2.5:1) at -10 degrees C and moderate H-2 and O-2 pressures. Molar yields in H2O2 after 1.5 hours, range from 12.9% [Pd(O)-Au(O)/resin] to 46% [Pd(O)/ K2621/H+].

引用

页码：255 / 259

页数：5

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