The pseudo-racemic complex bis[tris(2,2'-bipyridine)ruthenium(II)] hexacyanocobaltate(III) chloride octahydrate, [Ru(bpy)(3)](2)[Co(CN)(6)]Cl.8H(2)O

被引：15

作者：

Tamura, H ^{[1
]}

Ikeda, N ^{[1
]}

Iguro, T ^{[1
]}

Ohno, T ^{[1
]}

Matsubayashi, G ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196000042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals of [Ru(C10H8N2)(3)](2)[Co(CN)(6)]Cl.8H(2)O (C10H8N2 = bpy = 2,2'-bipyridine) which belong to the space group C2 are characterized by two 'pseudo-racemic' crystallographically independent [Ru(bpy)(3)](2+) cations. Three kinds of layers are found in the crystal structure: (i) a layer consisting of Lambda-[Ru(bpy)(3)](2+) cations and water molecules; (ii) a layer of [Co(CN)(6)](3-) and Cl- anions and water molecules; (iii) a layer of Delta-[Ru(bpy)(3)](2+) cations and water molecules. The layers are stacked in the order (i), (ii), (iii) and (ii) almost perpendicularly to the c axis. Some O ... O, O ... N(cyano) and O ... Cl hydrogen bonds construct networks within and between the layers.

引用

页码：1394 / 1399

页数：6

共 24 条

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