Efficient 2+3 cycloaddition approach to synthesis of pyridinyl based [60]fullerene ligands

被引:35
作者
Troshin, PA
Troyanov, SI
Boiko, GN
Lyubovskaya, RN
Lapshin, AN
Goldshleger, NF
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia
[3] RAS, Higher Chem Coll, Moscow 117901, Russia
关键词
azomethine ylids; fulleropyrrolidines; ZnTPP; fullerene-metalloporphyrin dyads;
D O I
10.1081/FST-120027200
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
[60]Fullerene reacts with azomethine ylids generated from 2- and 4-picolylamines to form corresponding fulleropyrrolidines bearing pyridinyl substituents. X-ray single crystal Structure of the first dyad formed via coordination of ZnTPP to the fulleropyrrolidine nitrogen is reported.
引用
收藏
页码:413 / 419
页数:7
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