VIII(OH){O2C-C6H4-CO2}•(HO2C-C6H4-CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology:: reticular synthesis with infinite inorganic building blocks?

被引：168

作者：

Barthelet, K ^{[1
]}

Marrot, J ^{[1
]}

Férey, G ^{[1
]}

Riou, D ^{[1
]}

机构：

[1] Univ Versailles, CNRS, UMR 8637, IREM, F-78035 Versailles, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b312589k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

V-III(OH){O2C-C6H4-CO2}.(HO2C-C6H4-O2H)(x)(DMF)(y)(H2O)(z) or MIL-68 was solvothermally synthesised in a non-aqueous medium. Its structure, built up from octahedral chains connected by terephthalate linkers, exhibits large hexagonal channels containing different occluded moieties. Their irreversible removal releases a specific surface area of 603(22) m(2).g(-1) (BET).

引用

页码：520 / 521

页数：2

共 16 条

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