Polydiacetylene supramolecules in electrospun microfibers: Fabrication, micropatterning, and sensor applications

被引:129
作者
Chae, Sang Kyun
Park, Hyunwook
Yoon, Jaewon
Lee, Cheol Hee
Ahn, Dong June
Kim, Jong-Man [1 ]
机构
[1] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
[2] Korea Univ, Dept Chem & Biol Engn, Seoul 136701, South Korea
关键词
D O I
10.1002/adma.200602012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer microfibers encapsulating polydiacetylene (PDA) supramolecules (see figure) are prepared by using the electrospinning technique. Randomly distributed diacetylene monomers are found to self-assemble during fiber formation and enable the generation of blue-colored PDA-containing polymer fibers upon UV irradiation. Micro-patterned images with a single fiber as well as the feasibility of a fiber-based sensor are demonstrated.
引用
收藏
页码:521 / +
页数:5
相关论文
共 33 条
[1]   LIPOSOMES FROM ALPHA,OMEGA-DIPOLAR AMPHIPHILES WITH A POLYMERIZABLE DIENE MOIETY IN THE HYDROPHOBIC CHAIN [J].
BADER, H ;
RINGSDORF, H .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (06) :1623-1628
[2]  
Carpick RW, 2000, LANGMUIR, V16, P4639, DOI 10.1021/1a991580k
[3]   DIRECT COLORIMETRIC DETECTION OF A RECEPTOR-LIGAND INTERACTION BY A POLYMERIZED BILAYER ASSEMBLY [J].
CHARYCH, DH ;
NAGY, JO ;
SPEVAK, W ;
BEDNARSKI, MD .
SCIENCE, 1993, 261 (5121) :585-588
[4]  
DERSCH R, 2004, POLYM ADVAN TECHNOL, V16, P1151
[5]   Spinning continuous fibers for nanotechnology [J].
Dzenis, Y .
SCIENCE, 2004, 304 (5679) :1917-1919
[6]   Water gelation by small organic molecules [J].
Estroff, LA ;
Hamilton, AD .
CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217
[7]   SUPRAMOLECULAR ASSEMBLIES OF DIACETYLENIC ALDONAMIDES [J].
FRANKEL, DA ;
OBRIEN, DF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) :10057-10069
[8]   Immunoglobulin-polydiacetylene sol-gel nanocomposites as solid-state chromatic biosensors [J].
Gill, I ;
Ballesteros, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (28) :3264-3267
[9]   UV polymerization of self-assembled monolayers of a novel diacetylene on silver: A spectroscopic analysis by surface plasmon resonance and surface enhanced Raman scattering [J].
Giorgetti, E ;
Muniz-Miranda, M ;
Margheri, G ;
Giusti, A ;
Sottini, S ;
Alloisio, M ;
Cuniberti, C ;
Dellepiane, G .
LANGMUIR, 2006, 22 (03) :1129-1134
[10]   In situ photo-cross-linking of cinnamate functionalized poly(methyl methacrylate-co-2-hydroxyethyl acrylate) fibers during electrospinning [J].
Gupta, P ;
Trenor, SR ;
Long, TE ;
Wilkes, GL .
MACROMOLECULES, 2004, 37 (24) :9211-9218