Oxide/polypyrrole composite films for corrosion protection of iron

被引：67

作者：

Garcia, B ^{[1
]}

Lamzoudi, A ^{[1
]}

Pillier, F ^{[1
]}

Le, HNT ^{[1
]}

Deslouis, C ^{[1
]}

机构：

[1] Univ Paris 06, CNRS, UPR 15, Lab Phys Liquides & Electrochim, F-75252 Paris 05, France

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2002年 / 149卷 / 12期

关键词：

D O I：

10.1149/1.1517581

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Oxide polypyrrole (PPy) composite films have been studied as protective coatings for iron. PPy films, containing strong oxidative species like oxide, have been obtained in order to maintain the polymer in its oxidized state which corresponds to the iron passive domain. Oxide particles in suspension in pyrrole/tetraoxalate solution have been embedded in PPy film during its electrodeposition. The films have been characterized by electrochemical quartz crystal microbalance, scanning electron microscopy, transmission electron microscopy, and tested in 3% NaCl corrosive medium. A significant improvement of the protection efficiency was obtained with PPy/iron oxide composite films and especially with PPy/Fe3O4 composite films. (C) 2002 The Electrochemical Society.

引用

页码：B560 / B566

页数：7

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