The tandem Diels-Alder reaction of dimethyl acetylenedicarboxylate to bicyclopentadiene. A theoretical study of the molecular mechanisms

被引：8

作者：

Domingo, LR ^{[1
]}

Arno, M ^{[1
]}

Andres, J ^{[1
]}

机构：

[1] UNIV JAUME 1, DEPT CIENCIAS EXPT, Castellon de La Plana 12080, SPAIN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 42期

关键词：

D O I：

10.1016/0040-4039(96)01832-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The molecular mechanisms for the tandem Diels-Alder reaction of dimethyl acetylenedicarboxylate to bicyclopentadiene have been studied by means of ab initio RHF/3-21G calculations. The first step of the pincer and domino reaction pathways present similar energy barriers and corresponds to the rate limiting step of both processes. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7573 / 7576

页数：4

共 9 条

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