Synthesis of copper nanoparticles catalyzed by pre-formed silver nanoparticles

被引:61
作者
Grouchko, Michael [1 ]
Kamyshny, Alexander [1 ]
Ben-Ami, Keren [1 ]
Magdassi, Shlomo [1 ]
机构
[1] Hebrew Univ Jerusalem, Casali Inst Appl Chem, Inst Chem, Ctr Nano Sci, IL-91904 Jerusalem, Israel
关键词
Silver; Copper; Nanoparticles; Catalysis; Colloids; PARTICLES; CU; TEMPLATE; WATER;
D O I
10.1007/s11051-007-9324-5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of well dispersed copper nanoparticles was achieved by reduction of copper nitrate in aqueous solution using hydrazine monohydrate as a reducer in the presence of preformed silver nanoparticles as catalysts. It has been demonstrated that addition of silver nanoparticles to the reaction mixture leads to formation of aqueous dispersion of copper nanoparticles and also results in a drastic reduction in reaction time compared to procedures reported in the literature. The absorption spectrum of the dispersions, HR-TEM and STEM images and XRD pattern indicate the formation of copper nanoparticles with particle size in the range of 5-50 nm.
引用
收藏
页码:713 / 716
页数:4
相关论文
共 23 条
[1]  
[Anonymous], RUSS CHEM REV
[2]  
CHRISTOPHER L, 2003, J PHYS CHEM B, V107, P11331
[3]   Synthesis, characterization, and properties of metallic copper nanoparticles [J].
Dhas, NA ;
Raj, CP ;
Gedanken, A .
CHEMISTRY OF MATERIALS, 1998, 10 (05) :1446-1452
[4]   Preparation and formation mechanisms of uniform metallic particles in homogeneous solutions [J].
Goia, DV .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (04) :451-458
[5]   PREPARATION OF POLYMER-PROTECTED COLLOIDAL DISPERSIONS OF COPPER [J].
HIRAI, H ;
WAKABAYASHI, H ;
KOMIYAMA, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (02) :367-372
[6]   Synthesis, characterization, and nonlinear optical properties of copper nanoparticles [J].
Huang, HH ;
Yan, FQ ;
Kek, YM ;
Chew, CH ;
Xu, GQ ;
Ji, W ;
Oh, PS ;
Tang, SH .
LANGMUIR, 1997, 13 (02) :172-175
[7]   Radiation induced synthesis and characterization of copper nanoparticles [J].
Joshi, SS ;
Patil, SF ;
Iyer, V ;
Mahumuni, S .
NANOSTRUCTURED MATERIALS, 1998, 10 (07) :1135-1144
[8]  
KAMYSHNY A, 2006, COLLOID STABILITY 1
[9]   Sonochemical synthesis of amorphous Cu and nanocrystalline Cu2O embedded in a polyaniline matrix [J].
Kumar, RV ;
Mastai, Y ;
Diamant, Y ;
Gedanken, A .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (04) :1209-1213
[10]   SYNTHESIS OF COPPER METALLIC CLUSTERS USING REVERSE MICELLES AS MICROREACTORS [J].
LISIECKI, I ;
PILENI, MP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :3887-3896