Metallo-supramolecular oligo(p-phenylene vinylene)/[60] fullerene architectures:: towards functional materials

被引:16
作者
El-ghayoury, A [1 ]
Schenning, APHJ [1 ]
van Hal, PA [1 ]
Weidl, CH [1 ]
van Dongen, JLJ [1 ]
Janssen, RAJ [1 ]
Schubert, US [1 ]
Meijer, EW [1 ]
机构
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
关键词
supramolecular chemistry; fullerenes; OPVs; ruthenium; terpyridine; electron transfer;
D O I
10.1016/S0040-6090(01)01561-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The assembly of pi-conjugated [oligo(p-phenylene vinylene)] OPV donors and [60]fullerene acceptor moieties into a supramolecular donor-acceptor system is achieved by ruthenium complexation. The synthesis and optical properties of a novel photoactive supramolecular dyad and triad are described to access the photoinduced formation of a charge-separated state. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:97 / 101
页数:5
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