Composition and chemical variability of the triterpene fraction of dichloromethane extracts of cork (Quercus suber L.)

被引:40
作者
Castola, V
Bighelli, A
Rezzi, S
Melloni, G
Gladiali, S
Desjobert, JM
Casanova, J
机构
[1] Univ Corse, CNRS, UMR 6134, Equipe Chim & BIomasse, F-20000 Ajaccio, France
[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
[3] Univ Corse, CNRS, UMR 6134, Lab Chim Prod Nat, F-20250 Corte, France
关键词
cork; extracts; C-13; NMR; chemometric analysis; chemical variability;
D O I
10.1016/S0926-6690(01)00091-7
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Dichloromethane extracts were prepared from 38 samples of cork harvested in different locations of Corsica and Sardinia from individual trees of Quercus suber L. Friedelin, 3-alpha -hydroxyfriedelan-2-one, betulin, betulinic acid, beta -sitosterol and sitost-4-en-3-one were identified and their molar percentages were calculated by C-13 NMR spectroscopy, following a procedure recently developed by our group. The results were submitted to chemometric analysis (k-means and principal component analysis), which allowed three groups to be distinguished with respect to the content of friedelin, betulinic acid and 3-alpha -hydroxyfriedelan-2-one. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:15 / 22
页数:8
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