Catalytic radical addition of carbonyl compounds to alkenes by Mn(II)/Co(II)O2 system

被引：51

作者：

Hirase, K

Iwahama, T

Sakaguchi, S

Ishii, Y ^{[1
]}

机构：

[1] Kansai Univ, Fac Engn, Dept Appl Chem, Osaka 5648680, Japan

[2] Kansai Univ, High Technol Res Ctr, Osaka 5648680, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 03期

关键词：

D O I：

10.1021/jo0162282

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The radical addition of enolizable carbonyl compounds such as malonates and malononitrile to alkenes was successfully achieved through a catalytic process using the Mn(II)/Co(II)/O-2 system to afford the corresponding adducts in fair to good yields. Dimethyl malonate added to 1,5-cyclooctadiene to produce a fused bicycle compound.

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页码：970 / 973

页数：4

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