Synthesis and characterization of a shock-synthesized cubic B-C-N solid solution of composition BC2.5N

被引:105
作者
Komatsu, T [1 ]
Nomura, M [1 ]
Kakudate, Y [1 ]
Fujiwara, S [1 ]
机构
[1] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN
关键词
D O I
10.1039/jm9960601799
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A cubic BC2.5N solid solution (c-BC2.5N) was synthesized in 18% yield by shock-compression of a hexagonal BC2.5N compound. c-BC2.5N was confirmed to have a diamond structure without a long range order of atomic arrangement. The material is a polycrystal composed of microcrystals of 5-20 nm in size. All constituent atoms are teterahedrally coordinated, giving C-C, C-B, C-N, and B-N bonds, and are homogeneously distributed on the lattice planes rather than showing a full short range order of atomic arrangement.
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页码:1799 / 1803
页数:5
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