Precursors towards poly-1,1′-ferrocenylacetylene:: a simple synthesis of hetero-disubstituted ferrocenylethynes

被引:20
作者
Butler, IR [1 ]
Boyes, AL [1 ]
Kelly, G [1 ]
Quayle, SC [1 ]
Herzig, T [1 ]
Szewczyk, J [1 ]
机构
[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales
关键词
ferrocene complexes; polymer complexes; ethyne complexes;
D O I
10.1016/S1387-7003(99)00099-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of key monomers for use in the synthesis of poly-1,1'-ferrocenylacetylene (polyferrocenylethyne, PFcE) has been achieved. The monomers an 1'-bromoferrocenylethyne and 1'-iodoferrocenylethyne, which were prepared from 1,1'-dibromo-and 1,1'-diiodoferrocene, respectively, in a simple two-step synthesis. This synthesis complements the pre-existing more elaborate methodology. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:403 / 406
页数:4
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