Methane oxidative coupling in an undiluted reaction mixture in a reactor-adsorber system with gas recirculation

被引：12

作者：

Machocki, A

机构：

[1] Maria Curie-Skłodowska Univ., Faculty of Chemistry, Department of Chemical Technology, 20031 Lublin

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 146卷 / 02期

关键词：

methane conversion; methane oxidative coupling; methane oxidative dimerization; reaction mixture without diluent; reaction products adsorption; gas recirculation; ethylene production;

D O I：

10.1016/S0926-860X(96)00178-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Results of the oxidative coupling of methane obtained in a reactor-adsorber system with gas recirculation, with a continuous supply of the methane-oxygen reaction mixture without a diluent gas (p(CH4 + O-2) = 1 atm, CH4:O-2 = 20:1), are described. At total methane conversion equal to 94%, the O-2, hydrocarbon selectivity of the process was 70%, while ethylene contents was 92% in the obtained hydrocarbons.

引用

页码：391 / 400

页数：10

共 28 条

[1] CONVERSION OF METHANE BY OXIDATIVE COUPLING [J].