An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(II) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block

被引：92

作者：

Gamez, P

de Hoog, P

Roubeau, O

Lutz, M

Driessen, WL

Spek, AL

Reedijk, J

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 14期

关键词：

D O I：

10.1039/b203394a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) nitrate reacts with the rigid polydentate triple-connecting dpyatriz ligand in acetonitrile to an unprecedented infinite molecular ladder in which five-coordinated copper pseudo-dimers are bridged by nitrate anions and the coordination polymer chains are linked by hexacoordinated copper ions leading to the formation of large guest cavities.

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页码：1488 / 1489

页数：2

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