Palladium(0) Nanoparticle Catalyzed Cross-Coupling of Allyl Acetates and Aryl and Vinyl Siloxanes

被引：57

作者：

Dey, Raju ^{[1
]}

Chattopadhyay, Kalicharan ^{[1
]}

Ranu, Brinclaban C. ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 23期

关键词：

D O I：

10.1021/jo802214m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling of allyl acetates and aryl and vinyl siloxanes proceeds readily by the catalysis of in situ generated palladium(0) nanoparticles. The reactions are stereoselective, and (E)-coupling products are obtained both from cis and trans allyl acetates. The coupling with vinyl siloxanes provides a novel protocol for the synthesis of 1,4-pentadienes.

引用

页码：9461 / 9464

页数：4

共 38 条

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