A highly selective fluoroionophore for the detection of lithium ions

被引：17

作者：

Benco, JS ^{[1
]}

Nienaber, HA ^{[1
]}

McGimpsey, WG ^{[1
]}

机构：

[1] Worcester Polytech Inst, Dept Chem & Biochem, Worcester, MA 01609 USA

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2004年 / 162卷 / 2-3期

关键词：

fluoroionophore; selectivity; lithium ions;

D O I：

10.1016/s1010-6030(03)00375-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

N-(9-methylanthracene)-25,27-bis(1-propyloxy)-4-tert-butylcalix[4]arene-azacrown-3 (I) was synthesized and tested as a fluoroionophore for the selective detection of lithium cations. The efficiency of photoinduced electron transfer in this fluoroionophore is sensitive to the presence of lithium ions. When exposed to lithium ions in a 75:25 (v/v) dichloromethane/THF solvent mixture, the molecule acted as an "off-on" fluorescence switch exhibiting a >106-fold enhancement in fluorescence emission intensity. Selectivity studies demonstrated that I effectively discriminates against sodium and potassium: log K-Li,K-Na = -3.8 and log K-Li,K-K = -2.3. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：289 / 296

页数：8

共 28 条

[1] CALIX[4]ARENES BLOCKED IN A RIGID CONE CONFORMATION BY SELECTIVE FUNCTIONALIZATION AT THE LOWER RIM
ARDUINI, A
FABBI, M
MANTOVANI, M
MIRONE, L
POCHINI, A
SECCHI, A
UNGARO, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05) : 1454 - 1457
[2] COMPARATIVE-EVALUATION OF NEUTRAL AND PROTON-IONIZABLE CROWN ETHER COMPOUNDS AS LITHIUM IONOPHORES IN ION-SELECTIVE ELECTRODES AND IN SOLVENT-EXTRACTION
ATTIYAT, AS
CHRISTIAN, GD
XIE, RY
WEN, XW
BARTSCH, RA
[J]. ANALYTICAL CHEMISTRY, 1988, 60 (23) : 2561 - 2564
[3] A fluoroionophore for detection of potassium ions: 9-anthryl-substituted azacrown ether covalently linked to a 1,3-alternate calix[4]arene
Benco, JS
Nienaber, HA
Dennen, K
McGimpsey, WG
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 152 (1-3) : 33 - 40
[4] SYNTHESIS, COMPLEXATION, AND MEMBRANE-TRANSPORT STUDIES OF 1,3-ALTERNATE CALIX[4]ARENE-CROWN-6 CONFORMERS - A NEW CLASS OF CESIUM SELECTIVE IONOPHORES
CASNATI, A
POCHINI, A
UNGARO, R
UGOZZOLI, F
ARNAUD, F
FANNI, S
SCHWING, MJ
EGBERINK, RJM
DEJONG, F
REINHOUDT, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) : 2767 - 2777
[5] 1,3-alternate calix[4]arenecrown-5 conformers: New synthetic ionophores with better K+/Na+ selectivity than valinomycin
Casnati, A
Pochini, A
Ungaro, R
Bocchi, C
Ugozzoli, F
Egberink, RJM
Struijk, H
Lugtenberg, R
deJong, F
Reinhoudt, DN
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (04) : 436 - 445
[6] de Namor AFD, 1998, CHEM REV, V98, P2495
[7] FLUORESCENT SIGNALING CROWN ETHERS - SWITCHING ON OF FLUORESCENCE BY ALKALI-METAL ION RECOGNITION AND BINDING INSITU
DE SILVA, AP
DESILVA, SA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) : 1709 - 1710
[8] Synthesis and sensing behavior of cyanoanthracene modified 1,3-alternate calix[4]benzocrown-6:: a new class of Cs+ selective optical sensors
Ji, HF
Dabestani, R
Brown, GM
Hettich, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (04): : 585 - 591
[9] Ji HF, 1999, PHOTOCHEM PHOTOBIOL, V69, P513, DOI 10.1111/j.1751-1097.1999.tb03321.x
[10] A new highly selective calix[4]crown-6 fluorescent caesium probe
Ji, HF
Dabestani, R
Brown, GM
Sachleben, RA
[J]. CHEMICAL COMMUNICATIONS, 2000, (10) : 833 - 834

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