Measurement and Analysis of Adhesion Property of Lithium-Ion Battery Electrodes with SAICAS

被引：110

作者：

Son, Bongki ^{[1
]}

Ryou, Myung-Hyun ^{[1
]}

Choi, Jaecheol ^{[1
]}

Lee, Taejoo ^{[1
]}

Yu, Hyung Kyun ^{[2
]}

Kim, Jong Hun ^{[2
]}

Lee, Yong Min ^{[1
]}

机构：

[1] Hanbat Natl Univ, Dept Chem & Biol Engn, Taejon 305719, South Korea

[2] LG Chem Ltd, Battery R&D, Taejon 305380, South Korea

来源：

ACS APPLIED MATERIALS & INTERFACES | 2014年 / 6卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

adhesion property; peel test; electrode; surface and interfacial cutting analysis system (SAICAS); lithium-ion batteries; NEGATIVE ELECTRODES; PERFORMANCE; ANODES; BINDER; CELLULOSE;

D O I：

10.1021/am404580f

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The adhesion strength of lithium-ion battery (LIB) electrodes consisting of active material, a nanosized electric conductor, and a polymeric binder is measured with a new analysis tool, called the Surface and Interfacial Cutting Analysis System (SAICAS). Compared to the conventional peel test with the same electrode, SAICAS gives higher adhesion strength owing to its elaborate cutting-based measurement system. In addition, the effects on the adhesion property of the polymeric binder type and content, electrode density, and measuring point are also investigated to determine whether SAICAS provides reliable results. The findings confirm SAICAS as an effective and promising tool to measure and analyze the adhesion properties of LIB electrodes.

引用

页码：526 / 531

页数：6

共 19 条

[1] Study of styrene butadiene rubber and sodium methyl cellulose as binder for negative electrodes in lithium-ion batteries [J].

Buqa, H. ;

Holzapfel, M. ;

Krumeich, F. ;

Veit, C. ;

Novak, P. .

JOURNAL OF POWER SOURCES, 2006, 161 (01) :617-622

[2] Binder effect on cycling performance of silicon/carbon composite anodes for lithium ion batteries [J].

Chen, Libao ;

Xie, Xiaohua ;

Xie, Jingying ;

Wang, Ke ;

Yang, Jun .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2006, 36 (10) :1099-1104

[3]

Fukumitsu H., 2012, P 53 BATT S JAP FAK

[4] Novolak resist removal by laser irradiation (532 nm) and adhesion between resist and substrate [J].

Horibe, H ;

Fujita, M ;

Nishiyama, I ;

Yoshikado, A .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (12) :8673-8675

[5] Friction and adhesion properties of fluorocarbon polymer thin films prepared by magnetron sputtering [J].

Iwamori, Satoru ;

Hasegawa, Norihiko ;

Uemura, Akihiro ;

Tanabe, Tomoya ;

Nishiyama, Itsuo .

VACUUM, 2009, 84 (05) :592-596

[6] A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries [J].

Koo, Bonjae ;

Kim, Hyunjung ;

Cho, Younghyun ;

Lee, Kyu Tae ;

Choi, Nam-Soon ;

Cho, Jaephil .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (35) :8762-8767

[7] A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries [J].

Kovalenko, Igor ;

Zdyrko, Bogdan ;

Magasinski, Alexandre ;

Hertzberg, Benjamin ;

Milicev, Zoran ;

Burtovyy, Ruslan ;

Luzinov, Igor ;

Yushin, Gleb .

SCIENCE, 2011, 334 (6052) :75-79

[8] Effect of carboxymethyl cellulose on aqueous processing of natural graphite negative electrodes and their electrochemical performance for lithium batteries [J].

Lee, JH ;

Paik, U ;

Hackley, VA ;

Choi, YM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (09) :A1763-A1769

[9] Depth profile analysis of ion-implanted photoresist by infrared spectroscopy [J].

Nagai, N ;

Imai, T ;

Terada, K ;

Seki, H ;

Okumura, H ;

Fujino, H ;

Yamamoto, T ;

Nishiyama, I ;

Hatta, A .

SURFACE AND INTERFACE ANALYSIS, 2002, 33 (07) :545-551

[10] Mechanical properties of a laminin-apatite composite layer formed on an ethylene-vinyl alcohol copolymer [J].

Oyane, Ayako ;

Yokoyama, Yoshiro ;

Kasahara, Mayumi ;

Ichinose, Noboru ;

Saito, Makoto ;

Ito, Atsuo .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2009, 29 (05) :1681-1686

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