Manganese-catalyzed reaction of gem-dibromoalkanes with Grignard reagents. Selective synthesis of alkenylsilanes

被引：27

作者：

Kakiya, H ^{[1
]}

Inoue, R ^{[1
]}

Shinokubo, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] KYOTO UNIV, FAC ENGN, DEPT CHEM MAT, SAKYO KU, KYOTO 60601, JAPAN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(97)00601-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of dibromomethyltrialkylsilanes with butylmagnesium bromide in the presence of a catalytic amount of manganese(II) chloride provided (E)-1-trialkylsilyl-1-pentenes with high stereoselectivity in good yields. (C) 1997 Elsevier Science Ltd.

引用

页码：3275 / 3278

页数：4

共 13 条

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