Carbon-ferrier rearrangements in ionic liquids using Yb(OTf)3 as catalyst

被引：26

作者：

Anjaiah, S

Chandrasekhar, S

Grée, R

机构：

[1] Ecole Natl Super Chim Rennes, CNRS, UMR 6052, Lab Synth & Activat Biomol, F-35700 Rennes, France

[2] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 214卷 / 01期

关键词：

ionic liquids; Carbon-Ferrier rearrangement; ytterbium triflate; glycal;

D O I：

10.1016/j.molcata.2003.10.063

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ionic liquids [bmim][BF4] and [bmim][NTf2] are used as efficient recyclable solvents in the ytterbium triflate catalysed carbon-Ferrier rearrangement of triacetyl glucal with allyl silanes, propargyl silane, and silyl enolethers. (C) 2004 Elsevier B.V. All rights reserved.

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页码：133 / 136

页数：4

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