A novel and efficient chiral palladium-phosphinooxazolidine catalyst for the enantioselective Diels-Alder reaction

被引：26

作者：

Nakano, H

Okuyama, Y

Suzuki, Y

Fujita, R

Kabuto, C

机构：

[1] Tohoku Pharmaceut Univ, Aoba Ku, Sendai, Miyagi 9818558, Japan

[2] Tohoku Univ, Grad Sch Sci, Instrumental Anal Ctr Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 10期

关键词：

D O I：

10.1039/b201625g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Easily prepared, chiral cationic palladium(II)-phosphinooxazolidine complexes are described which give excellent enantioselectivity (up to 98% ee) in the Diels-Alder reaction of cyclopentadiene with a range of acyl-1,3-oxazolidin-2-one dienophiles.

引用

页码：1146 / 1147

页数：2

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