Sulfated metal oxide catalysts - Superactivity through superacidity?

被引:57
作者
Brown, ASC [1 ]
Hargreaves, JSJ [1 ]
机构
[1] Nottingham Trent Univ, Dept Chem & Phys, Catalysis Res Lab, Nottingham NG11 8NS, England
关键词
D O I
10.1039/a807963c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sulfated metal oxides are a useful group of strong acid catalysts. The nature of their acidity, the identities of the active sites and their use in hydrocarbon transformation reactions are discussed.
引用
收藏
页码:17 / 20
页数:4
相关论文
共 24 条
[1]   ISOMERIZATION OF C-13 LABELED BUTANE OVER FE,MN PROMOTED SULFATED ZRO2 CATALYST [J].
ADEEVA, V ;
LEI, GD ;
SACHTLER, WMH .
APPLIED CATALYSIS A-GENERAL, 1994, 118 (01) :L11-L15
[2]  
ARATA K, 1996, APPL CATAL A-GEN, V46, P3
[3]  
Arata K., 1990, ADV CATAL, V37, P165
[4]  
BABOU F, 1994, STUD SURF SCI CATAL, V90, P519
[5]  
Brouwer D.M., 1972, PROGR PHYSICAL ORGAN, V9, P179, DOI DOI 10.1002/9780470171882.CH4
[6]   A study of the effect of sulphation on iron oxide catalysts for methane oxidation [J].
Brown, ASC ;
Hargreaves, JSJ ;
Rijniersce, B .
CATALYSIS TODAY, 1998, 45 (1-4) :47-54
[7]   A study of the structural and catalytic effects of sulfation on iron oxide catalysts prepared from goethite and ferrihydrite precursors for methane oxidation [J].
Brown, ASC ;
Hargreaves, JSJ ;
Rijniersce, B .
CATALYSIS LETTERS, 1998, 53 (1-2) :7-13
[8]   INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].
CORMA, A .
CHEMICAL REVIEWS, 1995, 95 (03) :559-614
[9]   Acidity and reactivity of sulfated zirconia and metal-doped sulfated zirconia [J].
Drago, RS ;
Kob, N .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (17) :3360-3364
[10]   Preparation of sulfated zirconia catalysts with improved control of sulfur content .2. Effect of sulfur content on physical properties and catalytic activity [J].
Farcasiu, D ;
Li, JQ ;
Cameron, S .
APPLIED CATALYSIS A-GENERAL, 1997, 154 (1-2) :173-184