A Boron-Containing PAH as a Substructure of Boron-Doped Graphene

被引：190

作者：

Dou, Chuandong ^{[1
,2
]}

Saito, Shohei ^{[1
,2
]}

Matsuo, Kyohei ^{[1
,2
]}

Hisaki, Ichiro ^{[3
]}

Yamaguchi, Shigehiro ^{[1
,2
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan

[2] Sci & Technol Agcy Furo, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, Suita, Osaka 565, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 49期

关键词：

boron; fluorescence; graphene; nanostructures; polycyclic aromatic hydrocarbons; POLYCYCLIC AROMATIC-HYDROCARBONS; HETEROCYCLIC-ANALOGS; CARBON; NANORIBBONS; PORPHYRINS; CHEMISTRY; CRYSTAL; SHEETS;

D O I：

10.1002/anie.201206699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

BBC news: Two boron atoms have been incorporated into a carbon nanosheet by a bottom-up synthesis to give a "B-doped nanographene" (see picture) with a defined structure. The experimental and theoretical analyses revealed the important role of the two boron atoms in producing its characteristic properties, such as broad absorption bands covering the visible region and reversible redox processes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12206 / 12210

页数：5

共 56 条

[1] Honeycomb Carbon: A Review of Graphene [J].

Allen, Matthew J. ;

Tung, Vincent C. ;

Kaner, Richard B. .

CHEMICAL REVIEWS, 2010, 110 (01) :132-145

[2]

[Anonymous], 2009, ANGEW CHEM

[3]

[Anonymous], ANGEW CHEM

[4] Graphene: Electronic and Photonic Properties and Devices [J].

Avouris, Phaedon .

NANO LETTERS, 2010, 10 (11) :4285-4294

[5] Electronic confinement and coherence in patterned epitaxial graphene [J].

Berger, Claire ;

Song, Zhimin ;

Li, Xuebin ;

Wu, Xiaosong ;

Brown, Nate ;

Naud, Cecile ;

Mayou, Didier ;

Li, Tianbo ;

Hass, Joanna ;

Marchenkov, Atexei N. ;

Conrad, Edward H. ;

First, Phillip N. ;

de Heer, Wait A. .

SCIENCE, 2006, 312 (5777) :1191-1196

[6]

Bosdet M. J. D., 2007, ANGEW CHEM, V119, P5028

[7] 10a-Aza-10b-borapyrenes: Heterocyclic analogues of pyrene with internalized BN moieties [J].

Bosdet, Michael J. D. ;

Piers, Warren E. ;

Sorensen, Ted S. ;

Parvez, Masood .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (26) :4940-4943

[8] Boron complexes of porphyrins and related polypyrrole ligands: unexpected chemistry for both boron and the porphyrin [J].

Brothers, Penelope J. .

CHEMICAL COMMUNICATIONS, 2008, (18) :2090-2102

[9] Atomically precise bottom-up fabrication of graphene nanoribbons [J].

Cai, Jinming ;

Ruffieux, Pascal ;

Jaafar, Rached ;

Bieri, Marco ;

Braun, Thomas ;

Blankenburg, Stephan ;

Muoth, Matthias ;

Seitsonen, Ari P. ;

Saleh, Moussa ;

Feng, Xinliang ;

Muellen, Klaus ;

Fasel, Roman .

NATURE, 2010, 466 (7305) :470-473

[10] Syntheses and structures of 6,13-dihydro-6,13-diborapentacenes:: π-stacking in heterocyclic analogues of pentacene [J].

Chen, Jinhui ;

Kampf, Jeff W. ;

Ashe, Arthur J., III .

ORGANOMETALLICS, 2008, 27 (15) :3639-3641

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