μ-oxo-bis{bis[2,2′-bis(1H-imidazole-N3)]oxorhenium(V)} tetrachloride hexahydrate

被引：21

作者：

Bélander, S ^{[1
]}

Beauchamp, AL ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S010827019801511X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The basic structural unit of the title compound, [{ReO(C6H6N4)(2)}(2)O]Cl-4. 6H(2)O, consists of a linear [Re2O3 (biimidazole)(4)](4+) cation whose O=Re-O-Re=O backbone lies on a twofold rotation axis. Octahedral coordination about each Re centre is completed by two chelating biimidazole ligands perpendicular to the backbone. Three Cl- anions are hydrogen bonded to the coordinated biimidazole ligands via N-H ... Cl bonds. The fourth anion is disordered over two positions and is connected to the rest of the structure via a chain of crystallization water molecules.

引用

页码：517 / 521

页数：5

共 22 条

[1] AHMED FR, 1973, J APPL CRYSTALLOGR, V6, P309
[2] SYNTHESIS AND X-RAY STRUCTURE OF A DIMERIC RHENIUM(V) COMPOUND - RE2O3CL4(3,5-MEPYRAZOLE)4.ME2CO
BACKESDAHMANN, G
ENEMARK, JH
[J]. INORGANIC CHEMISTRY, 1987, 26 (23) : 3960 - 3962
[3] Oxo ligand reactivity in the [ReO2L4](+) complex of 1-methylimidazole. Preparation and crystal structures of salts containing the ReOL4(3+) core and apical CH3O-, BF3O2-, and (CH3O)(2)PO2(-) groups
Belanger, S
Beauchamp, AL
[J]. INORGANIC CHEMISTRY, 1997, 36 (17) : 3640 - 3647
[4] Preparation and protonation studies of trans-dioxorhenium(V) complexes with imidazoles
Belanger, S
Beauchamp, AL
[J]. INORGANIC CHEMISTRY, 1996, 35 (26) : 7836 - 7844
[5] IRON(II) COMPLEXES OF 2,2'-BIIMIDAZOLE AND 2,2'-BIBENZIMIDAZOLE AS MODELS OF THE PHOTOSYNTHETIC MONONUCLEAR NONHEME FERROUS SITES - SYNTHESIS, MOLECULAR AND CRYSTAL-STRUCTURE, AND MOSSBAUER AND MAGNETIC STUDIES
BOINNARD, D
CASSOUX, P
PETROULEAS, V
SAVARIAULT, JM
TUCHAGUES, JP
[J]. INORGANIC CHEMISTRY, 1990, 29 (20) : 4114 - 4122
[6] COMPLEX COMPOUNDS OF TERTIARY PHOSPHINES AND A TERTIARY ARSINE WITH RHENIUM(V), RHENIUM(III), AND RHENIUM(II)
CHATT, J
ROWE, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (10): : 4019 - &
[7] Enraf-Nonius, 1989, CAD 4 SOFTW VERS 5 0
[8] SYNTHESES, SPECTROSCOPIC CHARACTERIZATIONS, AND X-RAY STRUCTURES OF NEW OS(ETA(2)-H-2) COMPOUNDS CONTAINING AZOLE LIGANDS
ESTERUELAS, MA
LAHOZ, FJ
ORO, LA
ONATE, E
RUIZ, N
[J]. INORGANIC CHEMISTRY, 1994, 33 (04) : 787 - 792
[9] SYNTHESIS, ELECTRON-PARAMAGNETIC RESONANCE, AND MAGNETIC STUDIES OF BINUCLEAR BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(III) COMPOUNDS WITH BRIDGING PYRAZOLATE, BIIMIDAZOLATE, AND BIBENZIMIDAZOLATE ANIONS
FIESELMANN, BF
HENDRICKSON, DN
STUCKY, GD
[J]. INORGANIC CHEMISTRY, 1978, 17 (08) : 2078 - 2084
[10] ON ENANTIOMORPH-POLARITY ESTIMATION
FLACK, HD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV): : 876 - 881

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