A new high-yield synthesis of Cl3P=NSiMe3, a monomeric precursor for the controlled preparation of high molecular weight polyphosphazenes

被引：100

作者：

Wang, B ^{[1
]}

Rivard, E ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 07期

关键词：

D O I：

10.1021/ic011125n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phosphoranimine, Cl3P=NSiMe3, was prepared using a new, high-yield (>80%), one-pot synthesis via oxidation of the chlorophosphine, Cl2PN(SiMe3)(2) with SO2Cl2 in ether. Cl3P=NSiMe3 is a valuable monomeric precursor in the synthesis of well-defined polyphosphazenes.

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页码：1690 / 1691

页数：2

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